Large Scale H2s Sulfur Removal Reactors by Biological Method Chinese Manufacturer

• Customization: Available
• Application Fields: New Energy
• Certification: RoHS, ISO
• Model NO.: Large scale H2S sulfur removal
• Condition: New
• Noise Level: Ultra Quiet
• Parts: Adsorption Tower
• Purpose: Gas Purification
• Capacity: Larger Than 5000m³/Day
• Processing Method: Biological Method
• Temperature: Normal
• Material: Fiber Reinforced Plastic
• Service Time: 30 Years
• Control: Automatic
• Technical Support: Available
• Reduced H2s Concentration: 100-200ppm
• Initial H2s Concentration: 100ppm~20000ppm
• Machine Size: Medium
• Usage: Sulfur Removal
• Transport Package: Standard Export Packing
• Specification: Customized
• Trademark: Mingshuo
• Origin: China
• HS Code: 84213990
• Production Capacity: 100 Sets/Year

Product Description

Biological desulfurization (BDS) is a process in which a sulfur-containing compound (H₂S, organic sulfur) is catalyzed by microorganisms or enzymes contained therein to convert it into elemental sulfur (S) and a trace amount of SO4²¯. With this biological desulfurization process, the efficiency can be higher than 99.5%.

Technically it belongs to separate biological desulfurization process, as it does not introduce exogenous gases such as air, oxygen into reaction, and the calorific value of biogas remains unchanged. It can be used for removal of H₂S in biogas, natural gas and industrial waste gas generated by anaerobic digestion of domestic garbage, livestock manure, kitchen waste and organic sewage. The desulfurization product is a high-purity elemental sulfur (S), which can be used for industrial production.

Principles for Biological Desulfurization: 
In the absorption tower, H2S containing gas is countercurrently contacted with the alkali solution which contains the sulfur bacteria. During this phase, H2S is dissolved in the alkaline solution , then enters into the bioreactor with lye, while purified gas gets out from the top. In the pneumatic bioreactor environment, sulfide (HS -) is oxidized to elemental sulfur by sulfur bacterium bacteria. Then the sulphur is withdrawn from the bioreactor in the form of a slurry which can be further dried into a powder or melted to form commercial sulphur. At the same time, the lye is regenerated during the production of elemental sulfur and then it's returned to the absorption tower for recycling.
The oxidation process to reduce sulfur ( H2S ) is carried out in a bioreactor, which ensures the biogas is not exposed to oxygen, so it's safer and more reliable. Moreover, the biogas is not mixed with impurity gas and does not reduce the calorific value of it.

The main reaction formula in biological desulfurization is as follows:
Absorption phase:
H₂S absorption: H₂S+OH^-=HS^-+H₂O
H₂S+CO₃^2-=HS^-+HCO₃^-
CO₂ absorption: CO₂+OH^-=HCO₃^-
Carbonate formation: HCO₃^-+OH^-=CO₃^2-+H₂O
Biological phase:
Sulfur formation: HS^-+1/2 O₂=S+OH^-
Sulfate formation: HS^-+2O₂=SO₄^2-+H⁺
Carbonate decomposition: CO₃^2-+H₂O=HCO₃^-+OH^-
Bicarbonate decomposition: HCO₃^-=CO₂+OH^-

Advantages:
High desulfurization efficiency 99.5%
Low working cost, low maintenance cost
No pollution with elemental sulfur
Stable performance, easy to control
Small land required
Suitable for large-scale, high sulfur-containing gas (100ppm~20000ppm)
 

Comparison	Dry Desulfurization	Wet Desulfurization	Biological Desulphurization
Application	Small and medium projects with gas less than 5000m³/day; Second high precision desulfurization after other methods	Large Gas Plant up to 100,000 m^3/ day; High sulfur content around 5g/Nm³	Large-scale, high sulfur-containing gas (100ppm~20000ppm)
Power Consumption	None	High	Moderate
Operating Cost	Moderate, the desulfurizer need to be changed periodically	Moderate	Low cost on electricity bill
Land Scale	Small	Full set of equipment for gas desulfurization, regeneration, filtration and melting sulfur, in result, large land is required.	Moderate
Operation Management	Easy to manage, reliable operation, dispense with staff on duty	Need people on duty to control the operation	Automatic operation, simple maintenance
Note	Refueling at fixed period, one use one reserve, alternate operation	Many equipment
Advantages	Simple structure, low investment, long lifetime, high precision of desulfurization (lower than 15ppm)	It can deal with large amount gas, and the system can run continuously by using PH value to keep the efficiency.	High desulfurization efficiency 99.5%, no second pollution, stable performance, suitable for large-scale, high sulfur-containing gas

Management System Certification: ISO9001:2008, ISO14001:2004, OHSAS18001:2007

Company Introduction: 
Shandong Mingshuo New Energy Technology Co., Ltd. Specializes in biogas project. The company is the production base of medium and large biogas equipments in China, the member of China Biogas Association, the member of China Association of Rural Energy Industry. The company is the recommended member of CCTV Website Enterprise Channel and China Import and Export Commodity Website, the most complete and excellent biogas equipments manufacturers in China. Mingshuo is a professional company integrating the scientific research, technological design, production and debugging service. The company specializes in the production of desulfurizer, desulfurization equipments and biogas equipments. Such as, Mingshuo MTZ biogas dedicated desulfurizer, MT ferric oxide desulfurizer, 889 wet desulfurization catalysts, water treatment agent, MS biogas dedicated desulfurization tanks, thioniers, biogas dedicated gas-water separators, assembled tanks, gas holders, positive-negative pressure protectors, biogas dedicated flame arresters, biogas boilers, deironing magnetic separation equipments, etc. 

Contact: Emma Luan
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Manufacturer & Supplier for Biogas Plant, Desulfurization System, Organic Waste Treatment Equipment etc.